In the mid 1960s, a group called The Detergents released an album of novelty songs, and a couple of them caught on, but one did especially well, a parody of the Shangri-Las' "Leader of the Pack." Among that group was a young man named Ron Dante.
A few years later, Dante was chosen to be the lead voice for a fictional band that was tied in with a cartoon series. That band was The Archies, and they had a short string of hits, peaking with "Sugar Sugar" in 1969. Dante provided all the male voices on "Sugar Sugar," and Toni Wine provided all the female voices. So yes, you appear to hear two women—one singing low and the other singing high—but in fact they're both Toni Wine.
Wine left the group around the time "Sugar Sugar" became a hit, and the female portion of The Archies' follow-up single was voiced by someone else. You'll just have to listen in to find out who that was.
The Archies, around the "Sugar Sugar" era. From Left to right: Toni Wine, Ron Dante, Jeff Barry, Hot Dog (taking a break from conducting), Ron Dante, Toni Wine. Heh.
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